diff --git a/sphinx/references.rst b/sphinx/references.rst index 0b367e1..b859a5c 100644 --- a/sphinx/references.rst +++ b/sphinx/references.rst @@ -297,7 +297,7 @@ Capacity Comment - the SI unit for electric charge is the coulomb (1 C = 1 A·s) but in practice, capacity is usually expressed in ampere hours (A·h) + the SI unit for electric charge is the coulomb (1 C = 1 A·s) but in practice, capacity is usually expressed in ampere hours (A·h) @@ -547,7 +547,7 @@ ChargeTransferCoefficient Comment - The cathodic transfer coefficient αc is defined as –(RT/nF)(dlnkc /dE), where kc is the electroreduction rate constant, E is the applied potential, and R, T, and F have their usual significance. This definition is equivalent to the other, -(RT/nF)(dln|jc |/dE), where jc is the cathodic current density corrected for any changes in the reactant concentration at the electrode surface with respect to its bulk value. + The cathodic transfer coefficient αc is defined as –(RT/nF)(dlnkc /dE), where kc is the electroreduction rate constant, E is the applied potential, and R, T, and F have their usual significance. This definition is equivalent to the other, -(RT/nF)(dln|jc |/dE), where jc is the cathodic current density corrected for any changes in the reactant concentration at the electrode surface with respect to its bulk value. @@ -1075,7 +1075,7 @@ DiffusionCurrent Comment - Diffusion current is governed by Fick’s Laws of diffusion. It is the principle on which many electroana- lytical methods are based, because the current is proportional to the bulk concentration of the diffusing species. I_{d} = z*F*A*D*\grad(c)_{x=0}, where z is the electron number of an electrochemical reaction, F the Faraday constant, A the electrode surface area, D the diffusion coefficient of electroactive substance, and (∂c/∂x)x=0 the gradient of the amount concentration at the electrode surface position x = 0. + Diffusion current is governed by Fick’s Laws of diffusion. It is the principle on which many electroana- lytical methods are based, because the current is proportional to the bulk concentration of the diffusing species. I_{d} = z*F*A*D*\grad(c)_{x=0}, where z is the electron number of an electrochemical reaction, F the Faraday constant, A the electrode surface area, D the diffusion coefficient of electroactive substance, and (∂c/∂x)x=0 the gradient of the amount concentration at the electrode surface position x = 0. @@ -1893,7 +1893,7 @@ FaradaicCurrent Comment - Current that is produced by other processes, for example by diffusion of charged species, is termed ‘non- faradaic current’. + Current that is produced by other processes, for example by diffusion of charged species, is termed ‘non- faradaic current’. @@ -2174,7 +2174,7 @@ InternalResistance - + @@ -2190,7 +2190,7 @@ InternalResistance - +
Elucidationimpedance of a linear circuit's Thévenin representationimpedance of a linear circuit's Thévenin representation
IEC Reference
CommentAccording to to Thévenin's theorem can any linear electric curcuit be replaced with a voltage source in series with an impedance. This impedance is for historical reasons termed "internal resistance".According to to Thévenin's theorem can any linear electric curcuit be replaced with a voltage source in series with an impedance. This impedance is for historical reasons termed "internal resistance".
@@ -3080,7 +3080,7 @@ PotentiometricSelectivityCoefficient Comment - The selectivity coefficient is determined by means of the potential difference of the ion- selective electrode in mixed solutions of the primary ion, A, and interfering ion, B (Fixed Interference Method) or, less desirably, in separate solutions of A and B (Separate Solution Method). The activities of the primary ion, A, and the interfering ion, B, at which K is determined should always be specified, as the value of K is defined by a modified Nikolsky-Eisenman equation. The smaller the value of K , the A,B greater the electrode’s preference for the primary ion, A. + The selectivity coefficient is determined by means of the potential difference of the ion- selective electrode in mixed solutions of the primary ion, A, and interfering ion, B (Fixed Interference Method) or, less desirably, in separate solutions of A and B (Separate Solution Method). The activities of the primary ion, A, and the interfering ion, B, at which K is determined should always be specified, as the value of K is defined by a modified Nikolsky-Eisenman equation. The smaller the value of K , the A,B greater the electrode’s preference for the primary ion, A. @@ -3414,7 +3414,7 @@ ResponseTimeAtAnISE - + @@ -3825,8 +3825,8 @@ StandardElectrodePotential - +
ElucidationDuration between the time when an ion-selective electrode and an external reference electrode (the two completing the ion-selective electrode cell) are brought into contact with a sample solution (or the time at which the activity of the ion of interest in solution is changed) and the first time at which the slope of the cell potential vs. time plot (ΔE/Δt) becomes equal to a limiting value selected on the basis of the experimental conditions and/or requirements concerning accuracy.Duration between the time when an ion-selective electrode and an external reference electrode (the two completing the ion-selective electrode cell) are brought into contact with a sample solution (or the time at which the activity of the ion of interest in solution is changed) and the first time at which the slope of the cell potential vs. time plot (ΔE/Δt) becomes equal to a limiting value selected on the basis of the experimental conditions and/or requirements concerning accuracy.
Comment
CommentE° is related to the standard Gibbs Energy of the electrode reaction, Δr -G° or ΔrG , written as a reduction with respect to that of the standard hydrogen electrode (SHE) E° = −ΔrG°/zF.E° is related to the standard Gibbs Energy of the electrode reaction, Δr + G° or ΔrG , written as a reduction with respect to that of the standard hydrogen electrode (SHE) E° = −ΔrG°/zF.
@@ -5203,7 +5203,7 @@ ButlerVolmerEquation Comment - i = i0 * (exp(alpha*n*F*eta/(R*T)) – exp(-(1-alpha)*n*F*eta/(R*T))) + i = i0 * (exp(alpha*n*F*eta/(R*T)) – exp(-(1-alpha)*n*F*eta/(R*T))) @@ -6168,7 +6168,7 @@ ConductivityCell Comment Formed, in theory, by two 1 cm2 reversible electrodes spaced 1 cm apart, providing a uniform distribution of electrical field. In practice, however, a number -of other configurations are used. + of other configurations are used. @@ -8378,7 +8378,7 @@ FaradaysFirstLawOfElectrolysis - + @@ -8851,7 +8851,7 @@ GlassyCarbonElectrode
Elucidationmass m of electrochemically-transformed substance is proportional to the charge Q passed, m ∝ Q.mass m of electrochemically-transformed substance is proportional to the charge Q passed, m ∝ Q.
Alternative Label(s)
- + @@ -9300,7 +9300,7 @@ IonicLiquidElectrolyte
Elucidationelectrode made of glassy carbon material with an intertwined graphitic ribbon structure, formed by pyrolysis of a resol precursor at temperatures up to 3000 °Celectrode made of glassy carbon material with an intertwined graphitic ribbon structure, formed by pyrolysis of a resol precursor at temperatures up to 3000 °C
Alternative Label(s)
- + @@ -10511,7 +10511,7 @@ NernstEinsteinEquation
ElucidationAn ionic liquid is an electrolyte composed of a salt that is liquid below 100 °C. Ionic liquids have found uses in electrochemical analysis, because their unconventional properties include a negligible vapor pressure, a high thermal and electrochemical stability, and exceptional dissolution properties for both organic and inorganic chemical species.An ionic liquid is an electrolyte composed of a salt that is liquid below 100 °C. Ionic liquids have found uses in electrochemical analysis, because their unconventional properties include a negligible vapor pressure, a high thermal and electrochemical stability, and exceptional dissolution properties for both organic and inorganic chemical species.
Alternative Label(s)
- + @@ -10523,7 +10523,7 @@ NernstEinsteinEquation - +
Elucidationan equation relating the limiting molar conductivity Λ_m^0 to the ionic diffusion coefficients.an equation relating the limiting molar conductivity Λ_m^0 to the ionic diffusion coefficients.
Wikipedia Reference
Comment\Lambda_m^0 = (F^2/(R*T)) * (v_{+} * z_{+}^2 * D_{+} + v_{–} * z_{–}^2 * D_{–})\Lambda_m^0 = (F^2/(R*T)) * (v_{+} * z_{+}^2 * D_{+} + v_{–} * z_{–}^2 * D_{–})
@@ -14324,7 +14324,7 @@ SilverElectrode Comment - Ag electrodes were first used in potentiometry for the determination of Cl−, Br−, I−, as well as for Ag+ ions, to which they are sensitive. + Ag electrodes were first used in potentiometry for the determination of Cl−, Br−, I−, as well as for Ag+ ions, to which they are sensitive. @@ -15759,7 +15759,7 @@ VentCap - + diff --git a/sphinx/ttl_to_rst.py b/sphinx/ttl_to_rst.py index 0a20bd4..96fbc0f 100644 --- a/sphinx/ttl_to_rst.py +++ b/sphinx/ttl_to_rst.py @@ -107,6 +107,9 @@ def entities_to_rst(entities: list[dict]) -> str: rst += indent + "\n" if value.startswith("http"): value = f"""{value}""" + value = value.encode('ascii', 'xmlcharrefreplace') + value = value.decode('utf-8') + value = value.replace('\n', '\n' + indent) rst += indent + "\n" rst += indent + "\n"
Elucidationcomponent fitted into the filling hole of a cell with a provision of allowing the venting of electrolysis gas from the cell¨component fitted into the filling hole of a cell with a provision of allowing the venting of electrolysis gas from the cell¨
IEC Reference" + key + "" + value + "